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Ternary Halogenidometalates M/E/X

The inclusion of transition metal M in main group halogenido metalates allows for the isolation of new anion motifs and each specific metal has a distinct influence on the electronic properties of the resulting compounds. These types of reactions can also be very challenging, as the competition from simple E/X and M/X compounds needs to be overcome by clever reaction design.

Check out our publications "Ternary Iodido Bismuthates and the Special Role of Copper" and "Divergent Optical Properties in an Isomorphous Family of Multinary Iodido Pentelates" for more information!