Main Content

Publications in peer-reviewed journals

  • Latest

    231. Laser-Driven One- and Two-Dimensional Subwavelength Periodic Patterning of Thin Films Made of a Metal−Organic MoS2 Precursor.
    S. Durbach, F. T. Krauss, M. Hoffmann, V. Lehmann, H. Reinhardt, J. Sundermeyer, N. Hampp, ACSNano 2022, XXXX, XXX, XXX–XXX. DOI: 10.1021/acsnano.2c00671

    230. Juglophen: A Tetradentate Non-Innocent Electron Sponge Naphthoquinone-imine Ligand and its Reduced and Oxidized Nickel Complex [Ni(jp)]-,0,+.
    H. Schumann, M. Klein, C. Prinzisky, O. Burghaus, J. Sundermeyer, Dalton Trans. 2022, 51, 9348–9356. DOI: 10.1039/D1DT03927J

    229. Lewis Acid-Base Adducts of Al(N(C6F5)2)3 and Ga(N(C6F5)2)3 – Structural Features and Adduct Formation Enthalpies.
    J. F. Kögel, D. A. Sorokin, M. Scott, K. Harms, D. Himmel, I. Krossing, J. Sundermeyer, Dalton Trans. 2022, 51, 4829–4835. DOI: 10.1039/d2dt00003b

    228. Rylene- and Diaza-rylene-derived Cobalt Clusters for the Solid-State Pyrolysis towards Undoped and N-doped Carbon Nanoparticles.
    S. Werner, T. Vollgraff, J. Sundermeyer, Dalton Trans. 2021, 50, 14374–14383. DOI: 10.1039/d1dt02276h

    227. Cyclopentadienylidene- and Fluoren-9-ylidene-methane-1,1-dithiolato Metalates of Tin, Indium and Bismuth.
    T. Vollgraff, N. Michel, J. Sundermeyer, Eur. J. Inorg. Chem. 2021, 37, 3852-3860. DOI: 10.1002/ejic.202100570

    226. Synthesis of Unsymmetrically Functionalized Violanthrenes by Reductive Aromatization of Violanthrone 79.
    S. Werner, J. Sundermeyer, Synlett 2021, 32, 1855–1860. DOI: 10.1055/a-1628-5664

    225. Design of Novel Uncharged Organic Superbases: Merging Basicity and Functionality.
    K. Vazdar, D. Margetić, B. Kovačević, J. Sundermeyer, I. Leito, U. Jahn, Acc. Chem. Res. 2021, 54, 15, 3108–3123. DOI: 10.1021/acs.accounts.1c00297

    224. Heavy Silylchalcogenido Lanthanates Ph4P[Cp3La-ESiMe3] (E = S, Se, Te) via Fluoride-Induced Demethylation of Dimethylcarbonate to Ph4P[OCO2Me] Key Intermediate.
    J. Guschlbauer, T. Vollgraff, X. Xie, A. Fetoh, J. Sundermeyer, Dalton Trans. 2021, 50, 13103–13111. DOI: 10.1039/D1DT02000E.

    223. Reductive O-Triflylation of Naphthalene Diimide: Access to Alkyne- and Amine-functionalized 2,7-Diazapyrenes.
    S. Werner, T. Vollgraff, Q. Fan, K. Bania, J. M. Gottfried, J. Sundermeyer, Org. Chem. Front. 2021, 8, 5013–5023. DOI: 10.1039/D1QO00862E

    222. Modular Design Strategy Towards Second Generation of Tridentate Carbodiphosphorane N,C,N Ligands with a Central 4-Electron Carbon Donor Motive and their Complexes.
    M. Klein, J. Sundermeyer, Organometallics 2021, 40(13), 2090–2099. DOI: 10.1021/acs.organomet.1c00231

    221. 2,9-Diazadibenzoperylene and 2,9-Dimethyldibenzoperylene-1,3,8,10-tetratriflates: Key to Functionalized 2,9-Diazaperopyrenes.
    E. Baal, M. Klein, K. Harms, J. Sundermeyer, Chem. Eur. J.  2021, 27, 12610–12618. DOI: 10.1002/chem.202101719

    220. Tetrasubstituted Peropyrenes Formed by Reductive Aromatization: Synthesis, Functionalization and Characterization.
    S. Werner, T. Vollgraff, J. Sundermeyer, Chem. Eur. J.  2021, 27, 11065–11075. DOI: 10.1002/chem.202101101

    219. Access to functionalized Pyrenes, Peropyrenes, Terropyrenes and Quarterropyrenes via Reductive Aromatization.
    S. Werner, T. Vollgraff, J. Sundermeyer, Angew. Chem. Int. Ed. 2021, 60, 13631–13635; Angew. Chem. 2021, 133, 13743–13748. DOI: 10.1002/anie.202100686; DOI: 10.1002/ange.202100686

    218. Highly Selective ortho-Directed Dicarboxylation of Cyclopentadiene by Methylcarbonates and CO2 or COS - First Insight into Co-ordination Chemistry of New Ambident Ligands.
    T. Vollgraff, J. Sundermeyer, Chem. Eur. J. 2021, 27, 8517– 8527. DOI: 10.1002/chem.202100300

    217. Heavy Chalcogenide-Based Ionic Liquids in Syntheses of Metal Chalcogenide Materials near Room Temperature.J. Guschlbauer, J. Sundermeyer, ChemistryOpen 2021, 10(2), 92–96. DOI: 10.1002/open.202000346

    216. Chalcogenido-dimethylgallates and -indates DMPyr2[Me2M(µ2-E)]2 (M = Ga, In; E = S, Se): Building Blocks for Higher and Lower Order Chalcogenidoindates.
    J. Guschlbauer, T. Vollgraff, L. H. Finger, K. Harms, J. Sundermeyer, ChemistryOpen 2021, 10(2), 83–91. DOI: 10.1002/open.202000347

    215. Kekulene: On-Surface Synthesis, Orbital Structure, and Aromatic Stabilization.
    A. Haags, A. Reichmann, Q. Fan, L. Egger, H. Kirschner, T. Naumann, S. Werner, T. Vollgraff, J. Sundermeyer, L. Eschmann, X. Yang, D. Brandstetter, F. Bocquet, G. Koller, A. Gottwald, M. Richter, M. Ramsey, M. Rohlfing, P. Puschnig, J. M. Gottfried, S. Soubatch, F. Tautz, ACS Nano 2020, 14(11), 15766–15775. DOI:10.1021/acsnano.0c06798

    214. A Series of Homoleptic Linear Trimethylsilylchalcogenido Cuprates, Argentates and Aurates Cat[Me3SiE-M-ESiMe3] (M = Cu, Ag, Au; E = S, Se).
    J. Guschlbauer, T. Vollgraff, X. Xie, F. Weigend, J. Sundermeyer, Inorg. Chem. 2020, 59(23), 17565–17572. DOI: 10.1021/acs.inorgchem.0c02808

    213. Cu(I) and Ag(I) Complexes with a New Type of Rigid Tridentate N,P,P-Ligand for Thermally Activated Delayed Fluorescence and OLEDs with High External Quantum Efficiency.
    M. Klein, N. Rau, M. Wende, J. Sundermeyer, G. Cheng, C.-M. Che, A. Schinabeck, H. Yersin, Chem. Mater. 2020, 32, 10365– 10382. DOI: 10.1021/acs.chemmater.0c02683

    212. Ortho-directed Dilithiation of Hexaphenyl-carbodiphosphorane.
    S. C. Böttger, C. Poggel, J. Sundermeyer, Organometallics 2020, 39, 3789–3793. DOI: 10.1021/acs.organomet.0c00458

    211. Di-ortho-beryllated Carbodiphosphorane: A Compound with a Metal–Carbon Double Bond to an Element of the s-Block.
    M. R. Buchner, S. Pan, C. Poggel, N. Spang, M. Müller, G. Frenking, J. Sundermeyer, Organometallics 2020, 39, 3224–3231. DOI: 10.1021/acs.organomet.0c00434

    210. Cu(I) Complexes of Multidentate N,C,N- and P,C,P-Carbodiphosphorane Ligands and Their Photoluminescence.
    M. Klein, N. Demirel, A. Schinabeck, H. Yersin, J. Sundermeyer, Molecules 2020, 25, 1–15. DOI: 10.3390/molecules25173990

    209. Solvent-Induced Bond-Bending Isomerism in Hexaphenyl Carbodiphosphorane: Decisive Dispersion Interactions in the Solid State.
    S. Böttger, M. Gruber, J. E. Münzer, G. M. Bernard, N.-J. H. Kneusels, C. Poggel, M. Klein, F. Hampe, B. Neumüller, J. Sundermeyer, V. K. Michaelis, R. Tonner, R. R. Tykwinski, I. Kuzu, Inorg. Chem. 2020, 59, 12054–12064. DOI: 10.1021/acs.inorgchem.0c00994

    208. Facile synthesis of an A3B-type phthalocyanine with a peripheral thiocatecholate binding group and its coordination to Ni(dppe): spectroscopy and theory.
    M. A. Bartlett, J. Sundermeyer, Dalton Trans. 2020, 49, 12180-12183. DOI: 10.1039/D0DT02060E

    207. Ionic liquid-based low-temperature synthesis of phase-pure tetradymite-type materials and their thermoelectric properties.
    M. Loor, S. Salloum, P. Kawulok, S. Izadi, G. Bendt, J. Guschlbauer, J. Sundermeyer, N. Pérez, K. Nielsch, G. Schierning, S. Schulz, Inorg. Chem. 2020, 59, 3428–3436 DOI: 10.1021/acs.inorgchem.9b03060

    206. Mono‐Phosphazenyl Phosphines (R2N)3P=N–P(NR2)2 – Strong P‐Bases, P‐Donors, and P‐Nucleophiles for the Construction of Chelates.
    J. F. Kögel, S. Ullrich, B. Kovačević, S. Wagner, J. Sundermeyer, Z. Anorg. Allg. Chem. 2020, 646, 923-932. DOI: 10.1002/zaac.202000108

    205. Homoleptic trimethylsilylchalcogenolato zincates [Zn(ESiMe3)3]− and stannanides [Sn(ESiMe3)3]− (E = S, Se): precursors in solution-based low-temperature binary metal chalcogenide and Cu2ZnSnS4 (CZTS) synthesis.
    J. Guschlbauer, T. Vollgraff, J. Sundermeyer, Dalton Trans. 2020, 49, 2517–2526. DOI: 10.1039/C9DT04144C

    204. On-Surface Synthesis and Characterization of a Cycloarene: C108 Graphene Ring.
    Q. Fan, D. Martin-Jimenez, S. Werner, D. Ebeling, T. Koehler, T. Vollgraff, J. Sundermeyer, W. Hieringer, A. Schirmeisen, J.M. Gottfried, J. Am. Chem. Soc. 2020, 142, 894–899. DOI: 10.1021/jacs.9b10151

    225. Design of Novel Uncharged Organic Superbases: Merging Basicity and Functionality.
    K. Vazdar, D. Margetić, B. Kovačević, J. Sundermeyer, I. Leito, U. Jahn, Acc. Chem. Res. 2021; published. DOI: 10.1021/acs.accounts.1c00297

    224. Heavy Silylchalcogenido Lanthanates Ph4P[Cp3La-ESiMe3] (E = S, Se, Te) via Fluoride-Induced Demethylation of Dimethylcarbonate to Ph4P[OCO2Me] Key Intermediate.
    J. Guschlbauer, T. Vollgraff, X. Xie, A. Fetoh, J. Sundermeyer, Dalton Trans. 2021; published. DOI: 10.1039/D1DT02000E.

    223. Reductive O-Triflylation of Naphthalene Diimide: Access to Alkyne- and Amine-functionalized 2,7-Diazapyrenes.
    S. Werner, T. Vollgraff, Q. Fan, K. Bania, J. M. Gottfried, J. Sundermeyer, Org. Chem. Front. 2021, advance article. DOI: 10.1039/D1QO00862E

    222. Modular Design Strategy Towards Second Generation of Tridentate Carbodiphosphorane N,C,N Ligands with a Central 4-Electron Carbon Donor Motive and their Complexes.
    M. Klein, J. Sundermeyer, Organometallics 2021, 40(13), 2090-2099. DOI: 10.1021/acs.organomet.1c00231

    221. 2,9-Diazadibenzoperylene and 2,9-Dimethyldibenzoperylene-1,3,8,10-tetratriflates: Key to Functionalized 2,9-Diazaperopyrenes.
    E. Baal, M. Klein, K. Harms, J. Sundermeyer, Chem. Eur. J.  2021, published. DOI: 10.1002/chem.202101719

    220. Tetrasubstituted Peropyrenes Formed by Reductive Aromatization: Synthesis, Functionalization and Characterization.
    S. Werner, T. Vollgraff, J. Sundermeyer, Chem. Eur. J.  2021; published. DOI: 10.1002/chem.202101101

    219. Access to functionalized Pyrenes, Peropyrenes, Terropyrenes and Quarterropyrenes via Reductive Aromatization.
    S. Werner, T. Vollgraff, J. Sundermeyer, Angew. Chem. Int. Ed. 2021, 60, 13631–13635; Angew. Chem. 2021, 133, 13743–13748. DOI: 10.1002/anie.202100686. DOI: 10.1002/anie.202100686; DOI: 10.1002/ange.202100686


  • 2019-2015

    203. Template-Controlled On-Surface Synthesis of a Lanthanide Supernaphthalocyanine and its Open-Chain Polycyanine Counterpart.
    Q. Fan, J.-N. Luy, M. Liebold, K. Greulich, M. Zugermeier, J. Sundermeyer, R. Tonner, J. M. Gottfried, Nature Commun. 2019, 10, 5049. DOI: 10.1038/s41467-019-13030-7

    202. Homoleptic Group 13 Trimethylsilylchalcogenolato Metalates [M(ESiMe3)4] (M = Ga, In; E = S, Se): Metastable Precursors for Low-Temperature Syntheses of Chalcogenide-Based Materials.
    J. Guschlbauer, T. Vollgraff, J. Sundermeyer, Inorg. Chem. 2019, 58, 15385–15392. DOI: 10.1021/acs.inorgchem.9b02453

    201. Basicity Enhancement by Multiple Intramolecular Hydrogen Bonding in Organic Superbase N,N′,N″,N‴-Tetrakis(3-(dimethylamino)propyl)triaminophosphazene.
    S. Ullrich, D. Barić, X. Xie, B. Kovačević, J. Sundermeyer, Org. Lett. 2019, 22, 9142–9146. DOI: 10.1021/acs.orglett.9b03521

    200. Quinoline-8-olato-chromium catalysts with pseudohalogen effects for the CO2/cyclohexene epoxide copolymerization.
    M. Hartweg, J. Sundermeyer, European Polymer Journal 2019, 120, 109245–109249. DOI: 10.1016/j.eurpolymj.2019.109245

    199. Synthesis and Characterization of a N,C,N-Carbodiphosphorane Pincer Ligand and Its Complexes.
    M. Klein, X. Xie, O. Burghaus, J. Sundermeyer, Organometallics 2019, 38, 3768–3777. DOI: 10.1021/acs.organomet.9b00489

    198. Design of non-ionic carbon superbases: second generation carbodiphosphoranes.
    S. Ullrich, B. Kovačević, B. Koch, K. Harms, J. Sundermeyer, Chem. Sci. 2019, 10, 9483–9492. DOI: 10.1039/c9sc03565f

    197. Systematic study on anion–cation interactions via doubly ionic H-bonds in 1,3-dimethylimidazolium salts comprising chalcogenolate anions MMIm [ER] (E = S, Se; R = H, tBu, SiMe3).
    J. Guschlbauer, T. Vollgraff, J. Sundermeyer, Dalton Trans. 2019, 48, 10971–10978. DOI: 10.1039/C9DT01586H

    196. Phosphazenyl phosphines PAP: The most electron rich uncharged phosphorus Brønsted and Lewis bases.
    S. Ullrich, B. Kovačević, X. Xie, J. Sundermeyer, Angew. Chem. Int. Ed. 2019, 58, 10335–10339; Angew. Chem. 2019, 131, 10443–10447. DOI: 10.1002/anie.201903342; DOI: 10.1002/ange.201903342

    195. Synthesis of Binam-P Derived C2-Symmetric bis-Iminophosphonamide Ligands. Molecular Structure of [(R)-Binam(Ph2PN(H)tBu)2].
    K. A. Rufanov, I. Y. Titov, A. R. Petrov, K. Harms, J. Sundermeyer, Z. Anorg. Allg. Chem. 2019, 645, 559–563. DOI: 10.1002/zaac.201800508

    194. H2O-Catalyzed Route to Early Lanthanide Tribromide THF and DME Solvates from Oxides.
    A. R. Petrov, N. K. Pruß, A. V. Churakov, K. A. Rufanov, J. Sundermeyer, Z. Anorg. Allg. Chem. 2019, 645, 679–682. DOI: 10.1002/zaac.201800509.

    193. Deep blue emitting Cu(I) tripod complexes - design of high quantum yield materials showing TADF-assisted phosphorescence.
    A. Schinabeck, N. Rau, M. Klein, J. Sundermeyer, H. Yersin, Dalton Trans. 2018, 47, 17067–17076. DOI: 10.1039/C8DT04093A

    192. Group 10 Metal-Thiocatecholate Capped Magnesium Phthalocyanines – Coupling Chromophore and Electron Donor/Acceptor Entities and its Impact on Sulfur Induced Red-Shifts.
    M. A. Bartlett, J. Sundermeyer, Dalton Trans. 2018, 47, 16255–16263. DOI: 10.1039/C8DT03681K

    191. Synthesis, spectroscopy and singlet oxygen quantum yield of a non-aggregating hexadecamethyl-substituted phthalocyanine silicon(IV) derivative.
    M. A. Bartlett, K. Mark, J. Sundermeyer, Inorg. Chem. Commun. 2018, 98, 41–43. DOI: 10.1016/j.inoche.2018.07.032

    190. An experimental and computational study on isomerically pure, soluble azaphthalocyanines and their complexes and boron azasubphthalocyanines of a varying number of aza units.
    M. Liebold, E. Sharikow, E. Seikel, L. Trombach, K. Harms, P. Zimcik, V. Novakova, R. Tonner, J. Sundermeyer, Org. Biomol. Chem. 2018, 16, 6586–6599. DOI: 10.1039/C8OB01705K

    189. Ferrocenyl-Sulfonium Ionic Liquids - Synthesis, Characterization and Electrochemistry.
    A. Venker, T. Vollgraff, J. Sundermeyer, Dalton Trans. 2018, 47, 1933–1941. DOI: 10.1039/C8OB01705K

    188. The Lewis superacid Al[N(C6F5)2]3 and its higher homolog Ga[N(C6F5)2]3 – structural
    features, theoretical investigation and reactions of a metal amide with higher fluoride ion affinity than SbF5.
    J. F. Kögel, D. A. Sorokin, A. Khvorost, M. Scott, K. Harms, D. Himmel, I. Krossing, J. Sundermeyer, Chem. Sci. 2018, 9, 245–253. DOI: 10.1039/C7SC03988C

    187. Electrochemical Kinetics of Ferrocene-Based Redox-ILs Investigated by Multi-Spectrum Impedance Fitting.
    J. Wallauer, K. Jähme, A. Venker, P. Kübler, J. Sundermeyer, B. Roling, J. Phys. Chem. C 2017, 121, 26706−26712. DOI: 10.1021/acs.jpcc.7b09693

    186. Electronic Structure of Titanylphthalocyanine Layers on Ag(111).
    A. Lerch, L. Fernández, M. Ilyn, M. Gastaldo, M. Paradinas, M. A. Valbuena, A. Mugarza, A. B. M. Ibrahim, J. Sundermeyer, U. Höfer, F. Schiller, J. Phys. Chem. C 2017, 121, 25353−25363. DOI: 10.1021/acs.jpcc.7b09147

    185. Structural Characterization of Neutral Saccharides by Negative Ion MALDI Mass Spectrometry Using a Superbasic Proton Sponge as Deprotonating Matrix.
    C. D. Calvano, T. R. I. Cataldi, J. F. Kögel, A. Monopoli, F. Palmisano, J. Sundermeyer, J. Am. Soc. Mass Spectrom. 2017, 28, 1666−1675. DOI: 10.1007/s13361-017-1679-y

    184. A Phosphorus Bisylide: Exploring a New Class of Superbases with Two Interacting Carbon Atoms as Basicity Centers.
    J. F. Kögel, D. Margetic, X. Xie, L. H. Finger, J. Sundermeyer,  Angew. Chem. Int. Ed. 2017, 56, 3090-3093, Angew. Chem. 2017, 129, 3136−3139. DOI: 10.1002/anie.201612446, DOI: 10.1002/ange.201612446
    Highlighted in ChemistryWorld (28.02.2017)

    183. New Lithium Borates with Bistetrazolato2- and Pyrazinediolato2- Ligands –
    Potentially Interesting Lithium Electrolyte Additives.
    L. H. Finger, A. Venker, F. G. Schröder, J. Sundermeyer, Dalton Trans. 2017, 46, 3014−3024. DOI: 10.1039/C7DT00308K

    182. Chelating P2-Bis-phosphazenes with a (R,R)-1,2-Diaminocyclohexane Skeleton: Two Novel Chiral Superbases.
    J. F. Kögel, B. Kovačević, S. Ullrich, X. Xie, J. Sundermeyer, Chem. Eur. J. 2017, 23, 2591−2598.
    DOI: 10.1002/chem.201604522

    181. Discrete nature of inhomogeneity: The initial stages and local configurations of TiOPc during bilayer growth on Ag(111).
    L. Fernandez, S. Thussing, A. Mänz, J. Sundermeyer, G. Witte, P. Jakob, Phys. Chem. Chem. Phys. 2017, 19, 2495−2502.
    DOI: 10.1039/C6CP07922A

    180. Novel nitrogen/gallium precursor [Ga(bdma)H2] for MOVPE.
    E. Sterzer, A. Beyer, L. Nattermann, W. Schorn, K. Schlechter, S. Pulz, J. Sundermeyer, W. Stolz, K. Volz, J. Cryst. Growth 2016, 454, 173–179. DOI: 10.1016/j.jcrysgro.2016.08.061

    179. Simple access to ionic liquids and organic salts containing the phosphaethynolate (PCO-) and
    Zintl (Sb113-) anions.
    M. Jost, L. H. Finger, J. Sundermeyer, C. von Hänisch, Chem. Commun. 2016, 52, 11646–11648. DOI: 10.1039/C6CC06620H

    178. N-Heterocyclic Olefin–Carbon Dioxide and –Sulfur Dioxide Adducts: Structures and Interesting Reactivity Patterns.
    L. H. Finger, J. Guschlbauer, K. Harms, J. Sundermeyer, Chem. Eur. J. 2016, 22, 16292–16303.  
    DOI: 10.1002/chem.201602973

    177. Mercurates from a Revised Ionothermal Synthesis Route: The Pseudo-Flux Approach.
    C. Donsbach, G. Thiele, L. H. Finger, J. Sundermeyer, S. Dehnen, Inorg. Chem. 2016, 55, 6725–6730. DOI: 10.1021/acs.inorgchem.6b00974

    176. Superbasic alkyl-substituted bisphosphazene proton sponges: a new class of deprotonating matrices for negative ion MALDI MS of low molecular weight hardly ionizable analytes.
    C. D. Calvano, T. R. I. Cataldi, J. F. Kögel, A. Monopoli, F. Palmisano, J. Sundermeyer, Rapid Commun. Mass Spectrom. 2016, 30, 1680–1686. DOI: 10.1002/rcm.7604

    175. Experimental Basicities of Phosphazene, Guanidinophosphazene, and Proton Sponge Superbases in the Gas Phase and Solution.
    I. Kaljurand, J. Saame, T. Rodima, I. Koppel, I. A. Koppel, J. F. Kögel, J. Sundermeyer, U. Köhn, M. P. Coles, I. Leito, J. Phys. Chem. A 2016, 120, 2591–2604. DOI: 10.1021/acs.jpca.6b01552

    174. Halide-Free Synthesis of Hydrochalcogenide Ionic Liquids Cat[HE] (E = S, Se, Te).
    L. H. Finger, J. Sundermeyer, Chem. Eur. J. 2016, 12, 4218–4230.  DOI: 10.1002/chem.201504577

    173. Anthraphen: A Novel Salphen-like Non-Innocent Tetradentate Anthraquinone Imine Dye, its Coordination and Electrochemistry.
    C. Prinzisky, A. Jacob, M. Harrer, M. Elfferding, J. Sundermeyer, Eur. J. Inorg. Chem. 2016, 2016, 477–489. DOI: 10.1002/ejic.201501355

    172. Formazanido Complexes of Heavier Group 13 Elements Aluminium, Gallium, and Indium.
    W. Schorn, D. Grosse-Hagenbrock, B. Oelkers, J. Sundermeyer, Dalton. Trans. 2016, 45, 1201–1207. DOI: 10.1039/C5DT03906A

    171. Simple Entry into N-tert-Butyl-Iminophosphonamide Rare-Earth Metal Alkyl and Chlorido Complexes.
    K. A. Rufanov, N. K. Pruß, J. Sundermeyer, Dalton Trans. 2016, 45, 1525–1538. DOI: 10.1039/C5DT03721B

    170. Li+ Ion Transport in Ionic Liquid-based Electrolytes and the Influence of Sulfonate-based Zwitterion Additives.
    F. Wohde, R. Bhandary, J. Moldrickx, J. Sundermeyer, M. Schönhoff, B. Roling, Solid State Ionics 2016, 284, 37–44. DOI: 10.1016/j.ssi.2015.11.017

    169. Optical and Electrochemical Properties of New Anthraquinone Imine Based Dyes for Dye-Sensitized Solar Cells.
    C. Prinzisky, I. Meyenburg, A. Jacob, B. Heidelmeier, F. Schröder, W. Heimbrodt, J. Sundermeyer, Eur. J. Org. Chem. 2016, 756–767.  DOI: 10.1002/ejoc.201501309

    168. A New Class of Deep Blue Emitting Cationic Cu(I) Complexes with a Tripodal Ligand – Effects of Counter Ions on the Emission Behavior.
    T. Gneuß, M. J. Leitl, L. H. Finger, H. Yersin, J. Sundermeyer, Dalton Trans. 2015, 44, 20045–20055. DOI: 10.1039/C5DT03065J

    167. Access to pure and highly volatile hydrochalcogenide ionic liquids.
    L. H. Finger, F. Wohde, E. I. Grigoryev, A.-K. Hansmann, R. Berger, B. Roling, J. Sundermeyer, Chem. Commun. 2015, 51, 16169–16172. DOI: 10.1039/C5CC06224A

    166. Synthesis of Organic (Trimethylsilyl)chalcogenolate Salts Cat[TMS-E] (E = S, Se, Te): the Methylcarbonate Anion as a Desilylating Agent.
    L. H. Finger, B. Scheibe, J. Sundermeyer, Inorg. Chem. 2015, 54, 9568–9575. DOI: 10.1021/acs.inorgchem.5b01665

    165. m-Rhodizonato-1kO,1:2kO',2kO''-tetra(triphenylphosphine)disilver(I):
    A Molecular Complex with the [C6O6]2- Ligand Template.
    L. H. Finger, J. Sundermeyer, Z. Anorg. Allg. Chem. 2015, 641, 2565–2569. DOI: 10.1002/zaac.201500589

    164. Fluoro- and Perfluoralkylsulfonylpentafluoroanilides: Synthesis and Characterization of NH Acids for Weakly Coordinating Anions and Their Gas-Phase and Solution Acidities.
    J. F. Koegel, T. Linder, F. G. Schroeder, J. Sundermeyer, S. K. Goll, D. Himmel, I. Krossing, K. Kuett, J. Saame, I. Leito, Chem. Eur. J. 2015, 21, 5769–5782. DOI: 10.1002/chem.201405391

    163. Fluorenylidene-Functionalized Lithium Phosphonium Di- and Triylides.
    F. G. Schroeder, J. Sundermeyer, Organometallics 2015, 34, 1017–1020. DOI: 10.1021/om501325h

    162. Synthesis an Characterization of 5-Cyanotetrazolide-Based Ionic Liquids.
    T. Bergholz, B. Oelkers, B. Huber, B. Roling, J. Sundermeyer, Chem. Eur. J. 2015, 21, 2613–2620. DOI: 10.1002/chem.201405264

    161. A new class of luminescent Cu(I) complexes with tripodal ligands – TADF emitters for the yellow to red color range.
    T. Gneuß, M. J. Leitl, L. H. Finger, N. Rau, H. Yersin, J. Sundermeyer, Dalton Trans. 2015, 44, 8506–8520. DOI: 10.1039/C4DT02631

  • 2014-2010

    160. Ruthenium Cyclopentadienylidene Phosphorane Complexes - Synthesis, Characterization and Catalysis.
    P. Kübler, B. Oelkers, J. Sundermeyer, J. Organomet. Chem. 2014, 767, 165–176. DOI: 10.1016/j.jorganchem.2014.06.002

    159. Highly active Cr(III) catalysts for the reaction of CO2 with epoxides.
    S. Elmas, M. A. Subhani, M. Harrer, W. Leitner, J. Sundermeyer, T. E. Müller, Cat. Sci. Tech. 2014, 4, 1652–1657. DOI: 10.1039/C3CY01087B

    158. Superbasic Alkyl-Substituted Bisphosphazene Proton Sponges - Synthesis, Structural Features, Thermodynamic and Kinetic Basicity, Nucleophilicity and Coordination Chemistry.
    J. F. Kögel, X. Xie, E. Baal, D. Gesevicius, B. Oelkers, B. Kovačević, J. Sundermeyer, Chem. Eur. J. 2014, 20, 7670–7685.
    DOI: 10.1002/chem.201402226

    157. Tetrahydropentalenyl-Phosphazene Constrained Geometry Complexes of Rare-Earth Metal Alkyls.
    N. K. Hangaly, A. R. Petrov, M. Elfferding, K. Harms, J. Sundermeyer, Dalton Trans. 2014, 43, 7109–7120. DOI: 10.1039/C3DT53596G

    156. Constrained Geometry Bisphosphazides Derived from 1,8-Diazidonaphthalene: Synthesis, Spectroscopic Characteristics, Structural Features, and Theoretical Investigations.
    J. F. Kögel, N. C. Abacilar, F. Weber, B. Oelkers, K. Harms, B. Kovačević, J. Sundermeyer, Chem. Eur. J. 2014, 20, 5994–6009. DOI: 10.1002/chem.201304498

    155. Two C2-Symmetric Chelating P2-Bisphosphazene Superbases Connected via a Binaphthyl Backbone – Synthesis, Structural Features and Preparation of a Cationic Alkyl Aluminum Complex.
    J. F. Kögel, N.-J. Kneusels, J. Sundermeyer, Chem. Commun. 2014, 50, 4319–4321. DOI: 10.1039/C4CC00773E

    154. The New NH-Acid HN(C6F5)(C(CF3)3) and Its Crystalline and Volatile Alkaline and Earth Alkaline Metal Salts.
    J. F. Kögel, L. H. Finger, N. Frank, J. Sundermeyer, Inorg. Chem. 2014, 53, 3839–3846. DOI: 10.1021/ic5001717
    Highlighted in C&EN 2014, 92, 34.?

    153. Ferrocenyl-Phosphonium Ionic Liquids - Synthesis, Characterization and Electrochemistry.
    P. Kübler, J. Sundermeyer, Dalton Trans. 2014, 43, 3750–3766. DOI: 10.1039/C3DT53402B

    152. Gas-phase oxycarbonylation of methanol for the synthesis of dimethylcarbonate using copper-based Supported Ionic Liquid Phase (SILP) Catalysts.
    M. J. Schneider, M. Haumann, M. Stricker, J. Sundermeyer, P. Wasserscheid, J. Catal. 2014, 309, 71–78. DOI: 10.1016/j.jcat.2013.08.029

    151. A New Synthetic Pathway to the Second and Third Generation of Superbasic Bisphosphazene Proton Sponges – The Run for the Best Chelating Ligand for a Proton.
    J. F. Kögel, B. Oelkers, B. Kovačević, J. Sundermeyer, J. Am. Chem. Soc. 2013, 135, 17768–17774. DOI: 10.1021/ja409760z

    150. Ion transport properties of ionic liquid-based polyelectrolytes.
    B. Huber, L. Rossrucker, J. Sundermeyer, B. Roling, Solid State Ionics 2013, 247–248, 15–21. DOI: 10.1016/j.ssi.2013.05.023

    149. Deprotonated P-ylides as Templates for Novel Cyclopentadienyl Phosphonioalkyl, -alkylidene, and -alkylidyne (CpPC) Constrained-Geometry Complexes.
    F. G. Schröder, C. Lichtenberg, M. Elfferding, J. Sundermeyer, Organometallics 2013, 32, 5082–5091. DOI: 10.1021/om4005548

    148. Synthesis and Characterisation of 5,5’-Bistetrazolate Salts with Alkali Metal, Ammonium and Imidazolium Cations.
    L. H. Finger, F. G. Schröder, J. Sundermeyer, Z. Anorg. Allg. Chem. 2013, 639, 1140–1152.
    DOI: 10.1002/zaac.201300150

    147. Stabilized Soluble Molybdenum(V) Imido Phthalocyanines and Pyrazinoporphyrazines: Crystal Structure, UV−Vis and Electron Paramagnetic Resonance Spectroscopic Studies.
    E. Seikel, B. Oelkers, O. Burghaus, J. Sundermeyer, Inorg. Chem. 2013, 52, 4451–4457. DOI: 10.1021/ic3026914

    146. Novel Stannylenes Stabilized with Diethylenetriamido and ­Related Amido Ligands: Synthesis, Structure, and Chemical Properties.
    M. Huang, M. M. Kireenko, E. K. Lermontova, A. V. Churakov, Y. F. Oprunenko, K. V. Zaitsev, D. Sorokin, K. Harms, J. Sundermeyer, G. S. Zaitseva, S. S. Karlov, Z. Anorg. Allg. Chem. 2013, 639, 502–511. DOI: 10.1002/zaac.201200552

    145. Copper(I) and Silver(I) Bis(trifluoromethanesulfonyl)imide and Their Interaction with an Arene, Diverse Olefins, and an NTf2−-Based Ionic Liquid.
    M. Stricker, B. Oelkers, C.-P. Rosenau, J. Sundermeyer, Chem. Eur. J. 2013, 19, 1042–1057. DOI: 10.1002/chem.201201740

    144. Synthesis of Novel Lithium Salts Containing Pentafluorophenylamido-based Anions and Investigation of their Thermal and Electrochemical Properties.
    B. Huber, T. Linder, K. Hormann, T. Frömling, J. Sundermeyer, B. Roling, Z. Phys. Chem. 2012, 226, 377–390. DOI: 10.1524/zpch.2012.0220

    143. Stabilized germylenes based on dialkanolamines: Synthesis, structure, chemical properties.
    M. Huang, M. M. Kireenko, K. V. Zaitsev, Y. F. Oprunenko, A. V. Churakov, J. A. K. Howard, M. V. Zabalov, E. K. Lermontova, J. Sundermeyer, T. Linder, S. S.Karlov, G. S. Zaitseva, J. Organomet. Chem. 2012, 706-707, 66–83. DOI: 10.1016/j.jorganchem.2012.01.018

    142. Yttrium Hydride Complex Bearing CpPN/Amidinate Heteroleptic Ligands: Synthesis, Structure, and Reactivity.
    Z. Jian, N. K. Hangaly, W. Rong, Z. Mou, D. Liu, S. Li, A. A. Trifonov, J. Sundermeyer, D. Cui, Organometallics 2012, 31, 4579–4587. DOI: 10.1021/om3003703

    141. New Lithium Phosphonium Diylides: A Methylene and a Cyclopentadienyl Moiety as Ylidic coordination Sites.
    C. Lichtenberg, N. S. Hillesheim, M. Elfferding, B. Oelkers, J. Sundermeyer, Organometallics 2012, 31, 4259–4266. DOI: 10.1021/om201182y

    140. Stabilized Germylenes Based on Diethylenetriamines and Related Diamines: Synthesis, Structures, and Chemical Properties.
    M. Huang, M. M. Kireenko, K. V. Zaitsev, Y. F. Oprunenko, A. V. Churakov, J. A. K. Howard, E. K. Lermontova, D. Sorokin, T. Linder, J. Sundermeyer, S. S.Karlov, G. S. Zaitseva, Eur. J. Inorg. Chem. 2012, 23, 3712–3724. DOI: 10.1002/ejic.201200363

    139. Molybdenum 1,4-Diazabuta-1,3-diene Tricarbonyl Solvento Complexes Revisited: From Solvatochromism to Attractive Ligand-Ligand Interaction.
    B. Oelkers, A. Venker, J. Sundermeyer, Inorg. Chem. 2012, 51, 4636–4643. DOI: 10.1021/ic202517w

    138. Phosphazene-Functionalized Cyclopentadienyl and Its Derivatives Ligated Rare-Earth Metal Alkyl Complexes: Synthesis, Structures, and Catalysis on Ethylene Polymerization.
    Z. Jian, A. R. Petrov, N. K. Hangaly, S. Li, W. Rong, Z. Mou, K. A. Rufanov, K. Harms, J. Sundermeyer, D. Cui, Organometallics 2012, 31, 4267–4282. DOI: 10.1021/om300263p

    137. Axial Functionalization of Sterically Hindered Titanium Phthalocyanines.
    E. Seikel, B. Oelkers, J. Sundermeyer, Inorg. Chem. 2012, 51, 2709−2717. DOI: 10.1021/ic202749v

    136. Cyclopentadienylphosphazene (CpPN) Complexes of Rare-Earth Metals: Synthesis, Structural Characterization, and Hydroamination Catalysis.
    N. K. Hangaly, A. R. Petrov, K. A. Rufanov, K. Harms, M. Elfferding, J. Sundermeyer, Organometallics 2011, 30, 4544−4554. DOI: 10.1021/om200264n

    135. Catena-Poly[[diacetonitrilecopper(I)]-m-dicyanamido].
    B. Oelkers, M. Stricker, J. Sundermeyer, Acta Cryst. 2011, E67, m1784. DOI: 10.1107/S1600536811047052

    134.  Sulfonate-tagged 1,4-diazabutadiene (DADS) ligands and their noble metal complexes – synthesis, characterization and immobilization in ionic liquids.
    B. Oelkers, J. Sundermeyer, Dalton Trans. 2011, 40, 12727−12741. DOI: 10.1039/C1DT10939A

    133. Synthesis and crystal structure of novel, soluble titanyl phthalocyanines.
    E. Seikel, M. Grau, R. Käsmarker, B. Oelkers, J. Sundermeyer, Inorg. Chim. Acta 2011, 347, 119−126. DOI: 10.1016/j.ica.2011.01.099

    132. Sulfinylamine metathesis at oxo metal species - convenient entry into imido metal chemistry.
    K. A. Rufanov, J. Kipke, J. Sundermeyer, Dalton Trans. 2011, 40, 1990−1997(Voted as HOT PAPER). DOI: 10.1039/C0DT01133A

    131. Synthesis and X-ray Crystal Structures of Imido and Ureato Derivatives of Titanium(IV) Phthalocyanine and their Application in the Catalytic Formation of Carbodiimides by Metathesis from Isocyanates.
    W. Darwish, E. Seikel, R. Käsmarker, K. Harms, J. Sundermeyer, Dalton Trans. 2011, 40, 1787–1794. DOI: 10.1039/C0DT00867B

    130.  Synthetic, Spectroscopic, and Structural Studies on Organoimido Molybdenum, Tungsten, and Rhenium Phthalocyanines.
    W. Darwish, E. Seikel, K. Harms, O. Burghaus, J. Sundermeyer, Dalton Trans. 2011, 40, 1183–1188. DOI: 10.1039/C0DT01166E

    129. Dichlorido(dimethyl sulfoxide-kS)(h6-mesitylene)ruthenium(II).
    B. Oelkers, L. H. Finger, J. Sundermeyer, Acta Cryst. E 2011, 67, m319–321. DOI: 10.1107/S160053681100314X

    128. Pentaalkylmethylguanidinium methylcarbonates via solvent-free synthesis - versatile precursors for the preparation of halide-free guanidinium-based ILs (GILs).
    B. Oelkers, J. Sundermeyer, Green Chem. 2011, 13, 608–618. DOI: 10.1039/c0gc00698j

    127. Dramatic enhancement of the stability of rare-earth metal complexes with a-methyl substituted N,N-dimethylbenzylamine ligands.
    A. R. Petrov, O. Thomas, K. Harms, K. A. Rufanov, J. Sundermeyer, J. Organomet. Chem. 2010, 695, 2738–2746. DOI: 10.1016/j.jorganchem.2010.09.042

    126. Spectroscopic and Computational Studies of an End-on Bound Superoxo-Cu(II) Complex: Geometric and Electronic Factors That Determine the Ground State.
    J. S. Woertink, L. Tian, D. Maiti, H. R. Lucas, R. A. Himes, K. D. Karlin, F. Neese, C. Würtele, M. C. Holthausen, E. Bill, J. Sundermeyer, S. Schindler, E. I. Solomon, Inorg. Chem. 2010, 49, 9450–9459. DOI: 10.1021/ic101138u

    125. Synthesis of chemisorbed imidazolium and phosphonium cations by reaction of ionic liquid precursors with silica.
    R. Lungwitz, T. Linder, J. Sundermeyer, I. Tkatchenko, S. Spange, Chem. Commun. 2010, 46, 5903–5905. DOI: 10.1039/C0CC00797H

    124. Cu(I)/(II) based catalytic ionic liquids, their metallo-laminate solid state structures and catalytic activities in oxidative methanol carbonylation.
    M. Stricker, T. Linder, B. Oelkers, J. Sundermeyer, Green Chem. 2010, 12, 1589–1598. DOI:10.1039/C003948A

    123. Unexpected Oxidative Dimerisations of a Cyclopentadienyl-Phosphane – Formation of Unprecedented, Structurally Remarkable Phosphacyclic Compounds.
    C. Lichtenberg, M. Elfferding, J. Sundermeyer, Eur. J. Inorg. Chem. 2010, 3117–3124. DOI: 10.1002/ejic.200901267

    122. Air-stable, Helical Bis-cyclopentadienyl-phosphazene (CpPN) Complexes of Divalent Ytterbium.
    A. R. Petrov, K. A. Rufanov, N. K. Hangaly, M. Elfferding, K. Harms, J. Sundermeyer, Mendeleev Commun. 2010, 20, 197–199. DOI: 10.1016/j.mencom.2010.06.004

    121. Neuartige Cyclopentadienyl-N-silylphosphazen-Komplexe der Seltenerdmetalle Yttrium und Lutetium.
    N. S. Hillesheim, M. Elfferding, T. Linder, J. Sundermeyer, Z. Anorg. Allg. Chem. 2010, 636, 1776–1782. DOI: 10.1002/zaac.201000078

    120. Investigation of Novel and Reinvestigation of Known Cyclopentadienylphosphanes: News on [1,5] Sigmatropic Rearrangements.
    C. Lichtenberg, M. Elfferding, L. Finger, J. Sundermeyer, J. Organomet. Chem. 2010, 695, 2000–2006. DOI: 10.1016/j.jorganchem.2010.05.001

    119. Discovery and Synthetic Value of a Novel, Highly Crowded Cyclopentadienyl-phosphane Ph2P-CpTM and its Ferrocenyl-bisphosphane dppfTM.
    A. R. Petrov, J. Möbus, M. Elfferding, K. Harms, K. Rufanov, J. Sundermeyer, Eur. J. Inorg. Chem. 2010, 4157–4165. DOI: 10.1002/ejic.200901266

  • 2009-2005

    118. Unexpected sp3-C-H Activation Upon Metallation of a New Cyclopentadienyl-N-silylphosphazene Ligand by the Yttrium Triaryl [Y(dmba)3].
    N. S. Hillesheim, J. Sundermeyer, Proceedings of the 7th International Conference on f Elements, ICfE-7, Ed. G. Meyer, Terrae Rarae 2009, 17, 1–5.

    117. Re-investigation of ortho-Metallated N,N-Dialkyllbenzylamine Complexes of
    Rare-Earth Metals. First Structurally Characterized Arylates of Neodyminum and Gadolinium Li[LnAr4].
    A. R. Petrov, K. A. Rufanov, K. Harms, J. Sundermeyer, J. Organomet. Chem. 2009, 694, 1212–1218. DOI: 10.1016/j.jorganchem.2008.12.020

    116. Intramolecular nucleophilic substitution in a C6F5 moiety. The fluoride-dialkylamino exchange in a decafluorodiphenylamino moiety.
    P. L. Shutov, S. S. Karlov, K. Harms, J. Sundermeyer, J. Lorberth, G. S. Zaitseva, J. Fluorine Chem. 2009, 130, 1017–1021. DOI: 10.1016/j.jfluchem.2009.08.006

    115. Three novel anions based on pentafluorophenyl amine combined with two new synthetic strategies for the synthesis of highly lipophilic ionic liquids.
    T. Linder, J. Sundermeyer, Chem. Commun. 2009, 2914–2916. DOI: 10.1039/B823153B

    114. Synthesis and Crystal Structures of Axially Substituted Titaniumphthalocyanines and Preparation of PcTi@SBA-15 and PcTi&TiOx@SBA-15 Materials..
    W. Darwish, S. Schlecht, A. Schaper, M. Fröba, K. Harms, W. Massa, J. Sundermeyer, Z. Anorg. Allg. Chem. 2009, 635, 1215–1224. DOI: 10.1002/zaac.200801289

    113. Enhanced lithium transference numbers in ionic liquid electrolytes.
    T. Frömling, M. Kunze, M. Schönhoff, J. Sundermeyer, B. Roling, J. Phys. Chem. B 2008, 112, 12985–12990. DOI: 10.1021/jp804097j

    112. Characterization of Three Members of the Electron-Transfer Series [Fe(pda)2]n (n = 2-, 1-, 0) by Spectroscopy and Density Functional Theoretical Calculations [pda = Redox Non-innocent Derivatives of N,N’-Bis(pentafluorophenyl)-o-phenylenediamide (2-, 1•-, 0)].
    M. M. Khusniyarov, E. Bill, Th. Weyhermüller, E. Bothe, K. Harms, J. Sundermeyer, K. Wieghardt, Chem. Eur. J. 2008, 14, 7608–7622. DOI: 10.1002/chem.200800546

    111. Synthesis and X-ray Crystal Structures of Acenaphthenequinone-based α-Diimine Palladium Complexes and a novel V-shape Tripalladium Cluster.
    J. Zhou, H. Sun, K. Harms, J. Sundermeyer, Z. Anorg. Allg. Chem. 2008, 634, 1517–1521. DOI: 10.1002/zaac.200800056

    110. Reaction of a Copper-Dioxygen Complex with Nitrogen Monoxide (•NO) Leads to a Copper(II)-Peroxynitrite Species.
    D. Maiti, D.-H. Lee, A .A. Narducci Sarjeant, M. Y. Pau, E. I. Solomon, K. Gautchenova, J. Sundermeyer, K. D. Karlin, J. Am. Chem. Soc. 2008, 130, 6700–6701. DOI: 10.1021/ja801540e

    109. A series of metal complexes with the non-innocent N,N’-bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure.
    M. M. Khusniyarov, K. Harms, O. Burghaus, J. Sundermeyer, B. Sarkar, W. Kaim, J. van Slageren, C. Duboc, J. Fiedler, Dalton Trans. 2008, 1355–1365. DOI: 10.1039/B714974C

    108. P-Amino-cyclopentadienylidene-phosphoranes versus P-cyclopentadienyl-iminophosphoranes - tautomeric protic forms of a new bidentate CpPN ligand system.
    A. R. Petrov, K. A. Rufanov, B. Ziemer, P. Neubauer, V. V. Kotov, J. Sundermeyer, Dalton Trans. 2008, 909–915. DOI: 10.1039/B710419G

    107. Reactions of a Copper(II) Superoxo Complex Lead to C-H and O-H Substrate Oxygenation: Modeling Copper-Monooxygenase C-H Hydroxylation.
    D. Maiti, D.-H. Lee, K. Gaoutchenova, C. Würtele, M. C. Holthausen, A. A. Narducci Sarjeant, J. Sundermeyer, S. Schindler, K. D. Karlin, Angew. Chem. Int. Ed. Engl. 2008, 47, 82–85; Angew. Chem. 2008, 120, 88–91. DOI: 10.1002/anie.200704389; DOI: 10.1002/ange.200704389

    106. Ortho-Directed Metathetical Fluoride/Amide Exchange in (Pentafluorphenyl)amides.
    P. L. Shutov, S. S. Karlov, K. Harms, M. V. Zabolov, J. Sundermeyer, J. Lorberth, G. S. Zaitseva, Eur. J. Inorg. Chem. 2007, 2007, 5684–5692. DOI: 10.1002/ejic.200700772

    105. Effect of different bases and phosphorus ylide on the selective deprotonation of phosphorus ylide adduct Cp*TaCl4(CH2=PPh3).
    X. Li, A. Wang, H. Sun, L. Wang, S. Schmidt, K. Harms, J. Sundermeyer, Organometallics 2007, 26, 3456–3460. DOI: 10.1021/om0701266

    104. Phosphorus ylide as a precursor for the formation of new high-valent tantalum phosphonio methylidyne complexes.
    X. Li, A. Wang, L. Wang, H. Sun, K. Harms, J. Sundermeyer, Organometallics 2007, 26, 1411–1413. DOI: 10.1021/om061068b

    103. Isotopic Probing of Molecular Oxygen Activation at Copper(I) Sites.
    M. P. Lanci, V. V. Smirnov, C. J. Cramer, E. V. Gauchenova, J. Sundermeyer, J. Roth, J. Am. Chem. Soc. 2007, 129, 14697–14709. DOI: 10.1021/ja074620c

    102. Volatile Imido-Hydrazido Compounds of the Refractory Metals Niobium, Tantalum, Molybdenum, and Tungsten.
    D. Gaess, K. Harms, M. Pokoj, W. Stolz, J. Sundermeyer, Inorg. Chem. 2007, 46, 6688–6701. DOI: 10.1021/ic062435e

    101. The transannular interaction germanium–nitrogen in germocanes: The influence of substituents.
    E. K. Lermontova, A. A. Selina, S. S. Karlov, A. V. Churakov, J .A. K. Howard, Y. F. Oprunenko, M. Y. Antipin, J. Sundermeyer, G. S. Zaitseva, J. Organomet. Chem. 2006, 691, 5722–5736. DOI: 10.1016/j.jorganchem.2006.08.011

    100. Molecular and Electronic Structures of Homoleptic Nickel and Cobalt Complexes with Noninnocent Bulky Diimine Ligands Derived from Fluorinated 1,4-Diaza-1,3-butadien (DAD) and Bis(arylimino)acenaphthene (BIAN).
    M. M. Khusniyarov, K. Harms, O. Burghaus, J. Sundermeyer, Eur. J. Inorg. Chem. 2006, 2006, 2985–2996. DOI: 10.1002/ejic.200600236

    99. Crystallographic Characterization of a Synthetic 1:1 End-On Copper Dioxygen Adduct Complex.
    C. Würtele, E. Gaoutchenova, K. Harms, M. C. Holthausen, J. Sundermeyer, S. Schindler, Angew. Chem. Int. Ed. 2006, 45, 3867–3869; Angew. Chem. 2006, 118, 3951–3954. DOI: 10.1002/anie.200600351; DOI: 10.1002/ange.200600351

    98. Formation of n2-Ketene Rhenium(VII) Complex through the C,C-Coupling Reaction of Phosphonio Methylidyne Complexes with Carbon Monoxide.
    X. Li, M. Schopf, J. Stephan,J. Kipke, K. Harms, J. Sundermeyer, Organometallics 2006, 25, 528–530. DOI: 10.1021/om050955w

    97. New highly fluorinated phenazine derivatives: correlation between crystal structure and NMR spectroscopy.
    M. M. Khusniyarov, K. Harms, J. Sundermeyer, J. Fluorine Chem. 2006,  127, 200–204. DOI: 10.1016/j.jfluchem.2005.10.018

    96. Aerobic Oxidation of Phenol to Quinone with Copper Chloride as Catalyst in an Ionic Liquid.
    H. Sun, X. Li, J. Sundermeyer, J. Mol. Catal. A, Chemical 2005, 240, 119–122. DOI: 10.1016/j.molcata.2005.06.041

    95. Characterization of a Stable Niobium(V) Phosphoniomethylidyne Complex.
    X. Li, H. Sun, K. Harms, J. Sundermeyer, Organometallics 2005, 24, 4699–4701. DOI: 10.1021/om0501172

    94. 1,8-Bis(hexamethyl-triamino-phosphazenyl)naphthalene, HMPN: A Superbasic Bisphosphazene "Proton Sponge".
    V. Raab, K. Gautchenova, A. Merkoulov, K. Harms, J. Sundermeyer, B. Kovačević, Z. B. Maksić, J. Am. Chem. Soc. 2005, 127, 15738–15743. DOI: 10.1021/ja052647v

    93. Synthesis and Structural Characterisation of 1,4-Diazadiene Imido Tungsten Complexes.
    A. Merkoulov, S. Schmidt, K. Harms, J. Sundermeyer, Z. Anorg. Allg. Chem. 2005, 631, 2877–2880. DOI: 10.1002/zaac.200500211

    92. Synthesis and Investigations on the Crystal Structure of a Dinuclear Diazadiene Molybdenum Oxo-Imido Complex with a Unique N3Mo(m-O)2MoN3 Core.
    A. Merkoulov, K. Harms, J. Sundermeyer, Eur. J. Inorg. Chem. 2005, 4902–4906.
    DOI: 10.1002/ejic.200400909

    91. A Lutetium Cyclopentadienyl-Phosphazene Constrained–Geometry Complex (CGC): First Isolobal Analogues of Group 4 Cyclopentadienyl-Silylamido CGC Systems.
    K. A. Rufanov, A. Petrov, V. V. Kotov, F. Laquai, J. Sundermeyer, Eur. J. Inorg. Chem. 2005, 3805–3807. DOI: 10.1002/ejic.200500529

    90. The crystal structure of a metal-containing ionic liquid: A new octachlorotricuprate(II).
    H. Sun, K. Harms, J. Sundermeyer, Z. Kristallogr. – Cryst. Mater. 2005, 220, 42–44. DOI: 10.1524/zkri.220.1.42.58889

    89. Mononuclear Imido Amido Complexes via Exhaustive Ammonolysis of Niobium and Tantalum Pentachloride with tert-Butyl Amine.
    A. Merkoulov, S. Schmidt, K. Harms, J. Sundermeyer, Z. Anorg. Allg. Chem. 2005, 631, 1810–1812. DOI: 10.1002/zaac.200500207

    88. 1,1-Dimethylhydrazinium chloride.
    A. Merkoulov, K. Harms, J. Sundermeyer, Acta Cryst. 2005, E61, o1800–o1801. DOI: 10.1107/S1600536805014856

    87. [N,N'-Diphenylureato(2-)][phthalocyaninato(2-)]titanium(IV).
    W. Darwish, K. Harms, J. Sundermeyer, Acta Cryst. 2005, E61, m1280–m1282. DOI: 10.1107/S1600536805015850

  • 2004-2000

    86. Aerobic Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone with Copper(II) Chloride as Catalyst in Ionic Liquid and Structure of the Active Species.
    H. Sun, K. Harms, J. Sundermeyer, J. Am. Chem. Soc. 2004, 126, 9550–9551. DOI: 10.1021/ja0391964

    85. Simple Synthesis of an Allenylidene Heptavalent Rhenium(d0) Complex.
    X. Li, M. Schopf, J. Stephan, J. Kipke, K. Harms, J. Sundermeyer, J. Am. Chem. Soc. 2004, 126, 8660–8661.
    DOI: 10.1021/ja048030f

    84. Combined Spectroscopic and Theoretical Evidence for a Persitent End-On Copper Superoxo Complex.
    M. Schatz, V. Raab, S. P. Foxon, G. Brehm, S. Schneider, M. Reiher, M. C. Holthausen, J. Sundermeyer, S. Schindler, Angew. Chem. Int. Ed. Engl. 2004, 43, 4360–4363; Angew. Chem. 2004, 116, 4460–4464. DOI: 10.1002/anie.200454125; DOI: 10.1002/ange.200454125

    83. Olefin Epoxidation with Inorganic Peroxides. Solutions to Four Long-Standing Controversies on the Mechanism of Oxygen Transfer.
    D. V. Deubel, G. Frenking, P. Gisdakis, W. A. Herrmann, N. Rösch, J. Sundermeyer, Acc. Chem. Res. 2004, 37, 645–652. DOI: 10.1021/ar0400140

    82. Formation of a Rhenium(VII) Phosphonio-Methylidyne Complex.
    X. Li, J. Stephan, K. Harms, J. Sundermeyer, Organometallics 2004, 23, 3359–3361. DOI: 10.1021/om049742h

    81. Tris[bis(trimethylsilyl)amido]samarium tetrahydrofuran solvate.
    J. Sundermeyer, A. Khvorost, K. Harms, Acta Cryst. 2004, E60, 1117–1119. DOI: 10.1107/S1600536804016435

    80. Intramolecular Nucleophilic Substitution in a C6F5 Moiety Assisted by Antimony.
    P. L. Shutov, S. S. Karlov, K. Harms, D. A. Tyurin, J. Sundermeyer, J. Lorberth, G. S. Zaitseva, Eur. J. Inorg. Chem. 2004, 2498–2503. DOI: 10.1002/ejic.200400074

    79. Lithium Bis(pentafluorophenyl)amide – Synthesis and Characterization of its Complexes with Diethyl Ether and THF.
    A. Khvorost, P. L. Shutov, K. Harms, J. Lorberth, J. Sundermeyer, S. S. Karlov, G. S. Zaitseva, Z. Anorg. Allg. Chem. 2004, 630, 885–889. DOI: 10.1002/zaac.200400041

    78. Diimido-, Imido(oxo)-, Dioxo- und Imido(alkyliden)-Halbsandwich-Verbindungen über selektive Hydrolyse und α-H-Abstraktion an Organylkomplexen des sechswertigen Molybdäns und Wolframs.
    U. Radius, G. Wahl, J. Sundermeyer, Z. Anorg. Allg. Chem. 2004, 630, 848–857. DOI: 10.1002/zaac.200400016

    77. 1,8-Bis(dimethylethyleneguanidino)naphthalene: Tailoring the Basicity of Bisguanidine "Proton Sponges" by Experiment and Theory.
    V. Raab, K. Harms, J. Sundermeyer, B. Kovačević, Z. B. Maksić, J. Org. Chem.  2003, 68, 8790–8797. DOI: 10.1021/jo034906+

    76. Recent Advances in the Synthesis of N-Heteroatom Substituted Imido Complexes Containing a Nitrido Bridge [M=N-E] (M = Group 4, 5 and 6 Metal, E = B, Si, Ge, P, S).
    K. Weber, K. Korn, A. Schorm, J. Kipke, M. Lemke, A. Khvorost, K. Harms, J. Sundermeyer, Z. Anorg. Allg. Chem. 2003, 629, 744–754. DOI: 10.1002/zaac.200390137

    75. Heavily p-Bond Loaded Tungsten Phosphonio-alkylidyne Complexes via a Domino Transylidation Cascade at Organoimido Tungsten Tetrachlorides.
    X. Li, M. Schopf, J. Stephan, K. Harms, J. Sundermeyer, Organometallics 2002, 21, 2356–2358. DOI: 10.1021/om020070+

    74. Sigma- versus Pi-Koordination in Bis-indenyl- und Bis-2-methallyl-Imidokomplexen des sechswertigen Molybdäns und Wolframs: DF-Rechnungen und Kristallstrukturanalyse.
    U. Radius, J. Sundermeyer, K. Peters, H. G. von Schnering, Z. Anorg. Allg. Chem. 2002, 628, 1226–1235. DOI: 10.1002/1521-3749(200206)628:5<1226::AID-ZAAC1226>3.0.CO;2-E

    73. Dimers of Highly p-Loaded Organoimido d1 Metal Radicals of Niobium, Tantalum, Molybdenum, Tungsten, and Rhenium: The Context of the Cyclopentadienyl Imido Ligand Analogy.
    U. Radius, A. Schorm, D. Kairies, S. Schmidt, F. Möller, H. Pritzkow, J. Sundermeyer, J. Organomet. Chem. 2002, 655, 96–104. DOI: 10.1016/S0022-328X(02)01423-7

    72. 1,8-Bis(tetramethylguanidino)naphthalene (TMGN): A New, Superbasic and Kinetically Active „Proton Sponge“.
    V. Raab, J. Kipke, R. M. Gschwind, J. Sundermeyer, Chemistry Eur. J. 2002, 8, 1682–1693. DOI: 10.1002/1521-3765(20020402)8:7<1682::AID-CHEM1682>3.0.CO;2-R

    71. Alkyl(amino)- and Alkyl(chloro)phosphanyl Substituted Cyclopentadienyl Complexes of Titanium and Zirconium.
    V. V. Kotov, E. V. Avtomonov, J. Sundermeyer, K. Harms, D. A. Lemenovskii, Eur. J. Inorg. Chem. 2002, 678–691. DOI: 10.1002/1099-0682(200203)2002:3<678::AID-EJIC678>3.0.CO;2-3

    70. Alkylaminophosphanyl Substituted Half-sandwich Complexes of Vanadium(III) and Chromium(III): Preparation and Reactivity in Ethylene Polymerisation.
    V. V. Kotov, E. V. Avtomonov, J. Sundermeyer, E. Aitola, T. Repo, D. A. Lemenovskii, J. Organomet. Chem. 2001, 640, 21–28. DOI: 10.1016/S0022-328X(01)01191-3

    69. Copper Complexes of Novel Superbasic Peralkylguanidine Derivatives of Tris(2-ethylamino)amine (Tren) as Constrained Geometry Ligands.
    V. Raab, J. Kipke, J. Sundermeyer, Inorg. Chem. 2001, 40, 6964–6971. DOI: 10.1021/ic010563r

    68. Silylimido Complexes of Niobium and Tantalum at the Limit of p-Bond Saturation.
    A. Schorm, J. Sundermeyer, Eur. J. Inorg. Chem. 2001, 2947–2955. DOI: 10.1002/1099-0682(200111)2001:11<2947::AID-EJIC2947>3.0.CO;2-%23

    67. Ligand Effects in The Copper Catalyzed Aerobic Oxidative Carbonylation of Methanol to Dimethyl Carbonate (DMC).
    V. Raab, M. Merz, J. Sundermeyer, J. Mol. Cat. A: Chem. 2001, 175, 51–63. DOI: 10.1016/S1381-1169(01)00220-5

    66. Olefin Epoxidation with Transition Metal n2-Peroxo Complexes: The Control of Reactivity.
    D. D. Deubel, J. Sundermeyer, G. Frenking, Eur. J. Inorg. Chem. 2001, 1819–1827. DOI: 10.1002/1099-0682(200107)2001:7<1819::AID-EJIC1819>3.0.CO;2-K

    65. Tripodale Bis(2,6-iminophosphoranyl)pyridin-Liganden: Eisen- und Cobalt-Komplexe mit Potential in der Ethen-Polymerisation.
    K. Kreischer, J. Kipke, M. Bauerfeind, J. Sundermeyer, Z. Anorg. Allg. Chem. 2001, 627, 1023–1028. DOI: 10.1002/1521-3749(200105)627:5<1023::AID-ZAAC1023>3.0.CO;2-A

    64. Complexes of Manganese, Iron, Zinc, and Molybdenum with a Superbasic Trisguanidine Derivative of Tris(2-ethylamino)amine (Tren) as Tripod Ligand.
    H. Wittmann, V. Raab, A. Schorm, J. Plackmeyer, J. Sundermeyer, Eur. J. Inorg. Chem. 2001, 1937–1948. DOI: 10.1002/1099-0682(200108)2001:8<1937::AID-EJIC1937>3.0.CO;2-I

    63. Bis(cyclopentadienyl) Diimido Complexes of Molybdenum and Tungsten [Cp2M(NR)2] at the Limit of p-Bond Saturation.
    U. Radius, J. Sundermeyer, K. Peters, H.-G. von Schnering, Eur. J. Inorg. Chem. 2001, 1617–1623. DOI: 10.1002/1099-0682(200106)2001:6<1617::AID-EJIC1617>3.0.CO;2-B

    62. Synthesis and Structure of a Series of New Haloaryl Imido Complexes of Molybdenum.
    K. A. Rufanov, D. N. Zarubin, N. A. Ustynyuk, D. N. Gourevitch, J. Sundermeyer, A. V. Churakov, J. A. K. Howard, Polyhedron 2001, 20, 379–385. DOI: 10.1016/S0277-5387(00)00605-7

    61. In Search of Catalytically Active Species in the Surfactant-Mediated Biphasic Alkene Epoxidation with Mimoun-Type Complexes.
    D. V. Deubel, J. Sundermeyer, G. Frenking, Organic Letters 2001, 3, 329–332. DOI: 10.1021/ol006775u

    60. Mechanism of the Olefin Epoxidation Catalyzed by Molybdenum Diperoxo Complexes: Quantum-Chemical Calculations Give an Answer to a Long-Standing Question.
    D. V. Deubel, J. Sundermeyer, G. Frenking, J. Am. Chem. Soc. 2000, 122, 10101–10108. DOI: 10.1021/ja0006649

    59. Interaction of t-Butyl Lithium and Triphenylmethylene Phosphoranes.
    K. Korth, J. Sundermeyer, Tetrahedron Lett. 2000, 41, 5461–5464. DOI: 10.1016/S0040-4039(00)00857-1

    58. On the Electronic Character of Oxygen-Transfer Reactions.
    D. V. Deubel, J. Sundermeyer, G. Frenking, J. Chem. Soc., Chem. Commun. 2000, 2469–2470. DOI: 10.1039/B006280O

    57. Theoretical Studies of Molybdenum Peroxo Complexes [MoOn(O2)3-n(OPH3)] as Catalysts for Olefin Epoxidation.
    D. V. Deubel, J. Sundermeyer, G. Frenking, Inorg. Chem. 2000, 39, 2314–2320. DOI: 10.1021/ic000204g

    56. Chelatliganden auf Basis peralkylierter Bis- und Tris-Guanidine.
    H. Wittmann, A. Schorm, J. Sundermeyer, Z. Anorg. Allg. Chem. 2000, 626, 1583–1590. DOI: 10.1002/1521-3749(200007)626:7<1583::AID-ZAAC1583>3.0.CO;2-3

    55. Novel Nitrido- and Oxo(phthalocyaninato) Complexes of Molybdenum, Tungsten and Rhenium.
    K. Frick, S. Verma, J. Sundermeyer, M. Hanack, Eur. J. Inorg. Chem. 2000, 1025–1030. DOI: 10.1002/(SICI)1099-0682(200005)2000:5<1025::AID-EJIC1025>3.0.CO;2-S

  • 1999-1995

    54. The first chiral diimido chelate complexes of molybdenum and tungsten: transition metal diimido complexes on the way to asymmetric catalysis.
    E. A. Kretzschmar, J. Kipke, J. Sundermeyer, J. Chem. Soc., Chem. Commun. 1999, 2381–2382. DOI: 10.1039/A907525I

    53. Peroxo Molybdenum Complexes as Epoxidation Catalysts in Biphasic Hydrogen Peroxide Activation: Raman Spectroscopic Studies and Density Functional Calculations.
    G. Wahl, D. Kleinhenz, A. Schorm, J. Sundermeyer, R. Stowasser, C. Rummey, G. Bringmann, C. Fickert, W. Kiefer, Chem. Eur. J. 1999, 5, 3237–3251. DOI: 10.1002/(SICI)1521-3765(19991105)5:11<3237::AID-CHEM3237>3.0.CO;2-O

    52. Sulfinylamid-Metathese und Nitren-Transfer an Komplexen des sechswertigen Molybdäns und Wolframs.
    K. Korn, A. Schorm, J. Sundermeyer, Z. Anorg. Allg. Chem. 1999, 625, 2125–2132. DOI: 10.1002/(SICI)1521-3749(199912)625:12<2125::AID-ZAAC2125>3.0.CO;2-Y

    51. Niob und Tantalkomplexe des N-metallierten Hexamethyl-imidophosphorsäuretriamids und des Tris-tert-butyliminophosphorans.
    K. Weber,  K. Korn, M. Schulz, J. Sundermeyer, Z. Anorg. Allg. Chem. 1999, 625, 1315–1320. DOI: 10.1002/(SICI)1521-3749(199908)625:8<1315::AID-ZAAC1315>3.0.CO;2-B

    50. New Chiral C3 -Symmetric Triols as Ligands for Vanadium and Titanium Complexes.
    H. Lütjens, G. Wahl, F. Möller, P. Knochel, J. Sundermeyer, Organometallics 1997, 16, 5869–5878. DOI: 10.1021/om970523o

    49. Vibrational Study of Oxo Complexes of Rhenium with Catalytic Activity: Normal Coordinate Analysis of H3C-ReO3 and [L-ReO3]+ {L = Ph3P=C=PPh3}.
    R. Pikl, K. Weber, J. Sundermeyer, W. A. Herrmann, W. Kiefer, Vibrational Spectrosc. 1997, 14, 299–302. DOI: 10.1016/S0924-2031(97)00006-4

    48. Synthesis of Tris(pyrazolyl)borate-Stabilized Vinyl, Allyl and Homoallyl Tungsten Oxides and their Selective Oxyfunctionalization by Singlet Oxygen and Dioxirane.
    W. Adam, J. Putterlik, R. Schuhmann, J. Sundermeyer, Organometallics 1996, 15, 4586–4596. DOI: 10.1021/om960366d

    47. Synthesis and reactivity of the formally co-ordinatively unsaturated dirhuthenium hydride [Ru2(µ-H)(µ-CO)(CO)3{µ-(iPrO)2PNEtP(OiPr)2}2]+ and its co-ordinatively saturated parent [Ru2H(CO)5{µ-(iPrO)2PNEtP(OiPr)2}2]+.
    K. J. Edwards, J. S. Field, R. J. Haines, B. D. Homann, M. W. Stewart, J. Sundermeyer, S. F. Woollam, J. Chem. Soc., Dalton Trans. 1996, 4171–4181. DOI: 10.1039/DT9960004171

    46. Activation of Bis(trimethylsilyl) Peroxide and tert-Butyl Hydroperoxide with Oxo and Peroxo Complexes of Vanadium, Molybdenum, and Tungsten for the Sulfoxidation of Thianthrene 5-Oxide.
    W. Adam, D. Golsch, J. Sundermeyer, G. Wahl, Chem. Ber. 1996, 129, 1177–1182. DOI: 10.1002/cber.19961291006

    45. The Bis(cyclopentadienyl)methane Link between Lewis Acidic and Lewis Basic Metal Centers.
    B. Stempfle, S. Schmidt, J. Sundermeyer, H. Werner, Chem. Ber. 1995, 128, 877–881. DOI: 10.1002/cber.19951280905

  • 1994-1990

    44. Oxidation of Diphosphazane-Bridged Derivatives of Dirhuthemium Nonacarbonyle by Silver(I) Carboxylates.
    J. S. Field, R. J. Haines, J. Sundermeyer, A. Wood, S. F. Woolam, Polyhedron 1994, 13, 3243–3251. DOI: 10.1016/S0277-5387(00)83387-2

    43. Diimidokomplexe [M(NR)2(PMe3)2(L)] des vierwertigen Molybdäns und Wolframs: Struktur, Moleküldynamik und Aktivierung p -acider Liganden.
    U. Radius, J. Sundermeyer, H. Pritzkow, Chem. Ber. 1994, 127, 1827–1835. DOI: 10.1002/cber.19941271003

    42. Homoscorpionate als tripodale Ankerliganden chlorfunktioneller Oxo- und Imidokomplexe von Elementen der 5. - 7. Gruppe.
    J. Sundermeyer, J. Putterlik, M. Foth, J. S. Field, N. Ramesar, Chem. Ber. 1994, 127, 1201–1212. DOI: 10.1002/cber.19941270705

    41. Higher-valent derivatives of the d-metal acids: XII. α-Phosphonio(methylidene) complexes of niobium and tantalum containing the metallocene-like [(η5-C5R5)M(NtBu)] core.
    S. Schmidt, J. Sundermeyer, F. Möller, J. Organomet. Chem. 1994, 475, 157–166. DOI: 10.1016/0022-328X(94)84018-0

    40. The Bonding Capability of Imido Complex Fragments of Groups 5–7 with Regard to the Isolobal Relationship.
    J. Sundermeyer, D. Runge, Angew. Chem. Int. Ed. Engl. 1994, 33, 1255–1257; Angew. Chem. 1994, 106, 1328–1331. 
    DOI: 10.1002/anie.199412551; DOI: 10.1002/ange.19941061216

    39. Höhervalente Derivate der d-Metall-Säuren X.Imidokomplexe des fünf- und vierwertigen Niobs und Tantals mit Halbsandwich- und Metallocen-Struktur.
    S. Schmidt, J. Sundermeyer, J. Organomet. Chem. 1994, 472, 127–138. DOI: 10.1016/0022-328X(94)80200-9

    38. Direct Metal–Metal Bonds Between High and Low Valent Complex Fragments: The Reaction of Metal Bases with the Metal Acids [Re(NR)3]+ und [Mo(NR)2]2+.
    J. Sundermeyer, D. Runge, J. S. Field, Angew. Chem. Int. Ed. Engl. 1994, 33, 678–681; Angew. Chem. 1994, 106, 679–682. DOI: 10.1002/anie.199406781; DOI: 10.1002/ange.19941060613

    37. Modeling Surface Reactivity of Metal Oxides: Synthesis and Structure of an Ionic Organorhenyl Perrhenate Formed by Ligand-Induced Dissociation of Covalent Re2O7.
    J. Sundermeyer, K. Weber, K. Peters, H. G. von Schnering, Organometallics 1994, 13, 2560–2562. DOI: 10.1021/om00019a008

    36. Reactions of Diphosphazane-Bridged Derivatives of Diruthenium Nonacarbonyl with Metal-Containing Electrophiles: Formation of the Solvento Species [Ru2(CO)5(solvent){m -(RO)2P(NEt)P(OR)2}2]2+  (R = Me or iPr) (R = Me or iPr)  and its Reactivity Towards Various Nucleophiles.
    D. W. Engel, J. S. Field, R. J. Haines, E. C. Horsfield, U. Honrath, J. Sundermeyer, S. F. Woollam, J. Chem. Soc., Dalton Trans. 1994, 1131–1143. DOI: 10.1039/DT9940001131

    35. Variable Co-ordination Behaviour of Ethyne and other Alkynes Towards the Diruthenium Complexes [Ru2(m-CO)(CO)4{m-(RO)2P(NEt)P(OR)2}2] and [Ru2(msb-CO)2(CO)2{m-(RO)2P(NEt)P(OR)2}2]  (sb = semi-bridging, R = Me or iPr).
    J. S. Field, R. J. Haines, J. Sundermeyer, S. F. Woollam, J. Chem. Soc., Dalton Trans. 1993, 3749–3757. DOI: 10.1039/DT9930003749

    34. Metal‐Mediated Oxyfunctionalization of Organic Substrates by Organometallic Intermediates—More Recent Developments and Perspectives.
    J. Sundermeyer, Angew. Chem. Int. Ed. Engl. 1993, 32, 1144–1146; Angew. Chem. 1993, 105, 1195–1197. DOI: 10.1002/anie.199311441; DOI: 10.1002/ange.19931050809

    33. Oxidation of Diphosphazane-bridged Derivatives of Diruthenium Nonacarbonyl by Silver(I) Salts in Protic Solvents: Synthesis, Structural Characterization and Protonation of the Adduct [Ru2{m-n2 -OC(O)}(CO)4{m-(RO)2P(NEt)P(OR)2}2]  (R = Me or iPr) involving a Novel Mode of Co-ordination of Carbon Dioxide.
    J. S. Field, R. J. Haines, J. Sundermeyer, S. F. Woollam, J. Chem. Soc., Dalton Trans. 1993, 2735–2748. DOI: 10.1039/DT9930002735

    32. Synthesis and Reactivity of the Unsaturated Diruthenium Diphosphazane-bridged Species [Ru2(CO)4{m-(RO)2P(NEt)P(OR)2}2] (R = Me or iPr).
    J. S. Field, R. J. Haines, M. W. Stewart, J. Sundermeyer, S. F. Woollam, J. Chem. Soc., Dalton Trans. 1993, 947–958. DOI: 10.1039/DT9930000947

    31. Synthesis of the First Stable 2‐Chromaoxetane and its Homologues via α‐Phosphonio(methylidene) Complexes of Hexavalent Chromium, Molybdenum, and Tungsten.
    J. Sundermeyer, K. Weber, H. Pritzkow, Angew. Chem. Int. Ed. Engl. 1993, 32, 731–733; Angew. Chem. 1993, 105, 751–753. DOI: 10.1002/anie.199307311; DOI: 10.1002/ange.19931050519

    30. Tris(3,5-dimethyl-1-pyrazolyl)boranato-substituierte Alkyl(dioxo)-, Methylen-phosphoranyl(dioxo)- und s-Allyl(dioxo)-Komplexe des Molybdäns und Wolframs.
    J. Sundermeyer, J. Putterlik, H. Pritzkow, Chem. Ber. 1993, 126, 289–296. DOI: 10.1002/cber.19931260204

    29. Unexpected ring-expansion of "axially prostereogenic" biaryl lactones by methylenephosphoranyl-substituted imido complexes of molybdenum and tungsten.
    J. Sundermeyer, K. Weber, H. Werner, N. Mahr, G. Bringmann, O. Schupp, J. Organomet. Chem. 1993, 444, C37–C40. DOI: 10.1016/0022-328X(93)83093-B

    28. (α-Triphenylphosphonio)methylidene Imido Complexes of Molybdenum, Tungsten and Rhenium: the First Complexes Exhibiting Metal-Ligand Multiple-bonding with Two Carbon as well as Two Nitrogen Centres.
    J. Sundermeyer, K. Weber, O. Nürnberg, J. Chem. Soc., Chem. Commun. 1992, 1631–1633. DOI: 10.1039/C39920001631

    27. Synthese und Reaktionen von Pentamethylcyclopentadienyl(imido)-Komplexen des Molybdäns und Wolframs und eine effiziente Strategie zur Synthese der Organometallate NBu4[Cp*MO3]  (M = Mo, W).
    J. Sundermeyer, U. Radius, Ch. Burschka, Chem. Ber. 1992, 125, 2379–2384. DOI: 10.1002/cber.19921251109

    26. Alkyl-, Aryl- und Cyclopentadienyl-substituierte Molybdän(VI)- und Wolfram(VI)-Imide.
    U. Radius, J. Sundermeyer, Chem. Ber. 1992, 125, 2183–2186. DOI: 10.1002/cber.19921251004

    25. Contrasting Pathways for the Reaction of the Electronacceptor Ligands Tetrachloro-1,2- and -1,4-benzoquinone with Diruthenium Diphosphazane-bridged Derivatives [Ru2(m-CO)(CO)4{m-(RO)2P(NEt)P(OR)2}2] (R = Me or iPr).
    J. S. Field, R. J. Haines, J. Sundermeyer, M. W. Stewart, S. F. Woollam, J. Chem. Soc., Dalton Trans. 1992, 3161–3162. DOI: 10.1039/DT9920003161

    24. Protonation of Diphosphazane Ligand-bridged Derivatives of Dirhuthenium Nonacarbonyl by Protic Acids with Co-ordinating and Non Co-ordinating Conjugate Bases.
    J. S. Field, R. J. Haines, E. Minshall, C. N. Sampson, J. Sundermeyer, S. F. Woollam, J. Chem. Soc., Dalton Trans. 1992, 2629–2639. DOI: 10.1039/DT9920002629

    23. Novel organometallic charge transfer salts derived from electron-rich diruthenium species and the electron-acceptor ligands 7,7,8,8-tetracyano-p-quinodimethane and tetracyanoethylene containing the radical anions of these ligands in both the inner and outer coordination spheres.
    S. E. Bell, J. S. Field, R. J. Haines, J. Sundermeyer, J. Organomet. Chem. 1992, 427, C1–C5. DOI: 10.1016/0022-328X(92)83212-Z

    22. Contrasting coordination behaviour of acetylene and other alkynes towards the diruthenium complexes [Ru2(m-CO)(CO)4{m-(RO)2P(NEt)P(OR)2}2] and [Ru2(CO)4{m-(RO)2P(NEt)P(OR)2}2]  (R= Me and iPr).
    J. S. Field, R. J. Haines, J. Sundermeyer, S. F. Woollam, S. Afr. J. Chem. 1992, 45, 1–4. pdf

    21. Synthesis and Reactivity of the Formally Unsaturated Diruthenium Diphosphazane-bridged Spezies [Ru2(CO)4{m-(iPrO)2P(NEt)P(OiPr)2}2]  (R = Me or iPr).
    J. S. Field, R. J. Haines, E. Minshall, J. Sundermeyer, S. F. Woollam, J. Chem. Soc., Chem. Commun. 1991, 1382–1384. DOI: 10.1039/C39910001382

    20. Electrophilic Attack on Diphosphazane-bridged Derivatives of Diruthenium Nonacarbonyl by Halogens. Crystal Structure of [Ru2(m-I)I(CO)3{m-(iPrO)2P(NEt)P(OiPr)2}2].
    J. S. Field, R. J. Haines, E. Minshall, C. N. Sampson, J. Sundermeyer, S. F. Woollam, C. C. Allen, J. C. A. Boeyens, J. Chem. Soc., Dalton Trans. 1991, 2761–2768. DOI: 10.1039/DT9910002761

    19. Neue Organometall-Imide des Molybdäns und Wolframs - die direkte Einführung der Cyclopentadienyl-Gruppe durch Maskierung der hohen Oxidationsstufe.
    J. Sundermeyer, Chem. Ber. 1991, 124, 1977–1979. DOI: 10.1002/cber.19911240915

    18. Chemie des Dicyans: Reaktionen von Diiminosuccinonitril (DISN) mit Sulfenylchloriden und Chlortrimethylsilan sowie Cyclisierung zu Trifluormethyl-substituierten 2H-Imidazolen.
    J. Sundermeyer, H. W. Roesky, Chem. Ber. 1991, 124, 1517–1520. DOI: 10.1002/cber.19911240706

    17. Synthesis of the Solvento Species [Ru2(CO)5(solvent){m-(RO)2P(NEt)-P(OR)2}2]2+ and its Potential as a Source for a Wide Range of Dinuclear Derivatives of Ruthenium.
    J. S. Field, R. J. Haines, U. Honrath, J. Sundermeyer, S. F. Woollam, J. Organomet. Chem. 1990, 395, C9–C15. DOI: 10.1016/0022-328X(90)85269-5

    16. Ready Deprotonation of the Protic Solvento Species [Ru2(CO)5(R'OH){m-(RO)2P(NEt)P(OR)2}2]2+  (R= Me or iPr ; R'= H, Me, Et,  etc.) and the Formation of [Ru2{m-OC(O)}(CO)4{m-(RO)2P(NEt)P(OR)2}2] Containing Carbon Dioxide in a Bridging Coordination Mode.
    J. S. Field, R .J. Haines, J. Sundermeyer, S. F. Woollam, J. Chem. Soc., Chem. Commun. 1990, 985–988. DOI: 10.1039/C39900000985

    15. Synthesis of Three-, Four- and Five-Membered Dimetallo-Heterocyclic Compounds by Reaction of the Hydride [Ru2H(CO)5{m -(RO)2PN(Et)P(OR)2}2][PF6] (R= Me or iPr) with Unsaturated Systems of the Type XºY and X=Y=Z. Crystal Structures of Representative Examples of the Three Types of Products.
    K. J. Edwards, J. S. Field, R. J. Haines, B. Homann, J. Sundermeyer, S. F. Woollam, J. Organomet. Chem. 1990, 386, C1–C6. DOI: 10.1016/0022-328X(90)80263-Y

    14. [2+3]-Cycloadditionsreaktionen von Nitrilen mit Bis(triphenylphosphoranyliden)iminiumazid.
    J. Sundermeyer, H. W. Roesky, M. Noltemeyer, Z. Naturforsch. 1990, 45B, 77–79. pdf

    13. Neue Synthesen Trifluormethyl-substituierter Heterocyclen.
    G. Rabe, J. Sundermeyer, H. W. Roesky, H.-G. Schmidt, M. Noltemeyer, Chem. Ber. 1990, 123, 691–696. DOI: 10.1002/cber.19901230407

    12. Reaktionen von 2,2,4,4-Tetrakis(trifluormethyl)-1,3-dithietan mit KNCS und KNCO - Struktur des Triphenylphosphan-Gold(I)- Komplexes eines Thiazolin-4-thiolats.
    J. Sundermeyer, H. W. Roesky, J. Lautner, P. G. Jones, Chem. Ber. 1990, 123, 433-438. DOI: 10.1002/cber.19901230304

  • 1989-1985

    11. Heterobimetallic Cluster Cations from the Reactions of Diphosphazane-Bridged Derivatives of [Ru2(CO)9] with Metal-Containing Electrophiles:  Mechanism of the One-Electron Oxidation of [Ru2(m-CO)(CO)4{m-(RO)2P(NEt)P(OR)2}2] by Silver Salts.
    D. W. Engel, R. J. Haines, E. C. Horsfield, J. Sundermeyer, J. Chem. Soc., Chem. Commun. 1989, 1457–1459.
    DOI: 10.1039/C39890001457

    10. Synthesis of a New Unsaturated 16-Membered Heterocycle with Alternating CC- and NS-Building Blocks.
    J. Sundermeyer, H. W. Roesky, M. Noltemeyer, Can. J. Chem. 1989, 67, 1785–1787. DOI: 10.1139/v89-276

    9. S4(CN)8, a Blue‐Black High‐Molecular Sulfur–Cyanogen Compound with 6π‐ and 8π‐Electron Structural Elements.
    J. Sundermeyer, H. W. Roesky, M. Noltemeyer, Angew. Chem. Int. Ed. Engl. 1989, 28, 609–610; Angew. Chem. 1989, 101, 609–610. DOI: 10.1002/anie.198906091; DOI: 10.1002/ange.19891010509

    8. Catalytic Syntheses of Functionalized Nitrogen Heterocycles from Cyanogen.
    J. Sundermeyer, H. W. Roesky, Angew. Chem. Int. Ed. Engl. 1988, 27, 1372–1373; Angew. Chem. 1988, 100, 1417–1418. DOI: 10.1002/anie.198813721; DOI: 10.1002/ange.19881001030

    7. The Formal Umpolung Behaviour of Protonic Acids Containing Coordinating Anions towards Diphosphazane-Bridged Derivatives of Nonacarbonyl-diruthenium.
    J. S. Field, R. J. Haines, E. Minshall, C. N. Sampson, J. Sundermeyer, J. Organomet. Chem. 1987, 327, C18–C24. DOI: 10.1016/0022-328X(87)80239-5

    6. Protonation of a Series of Diphosphazane- and Diphosphine-Bridged Derivatives of Iron- and Ruthenium Nonacarbonyl:  Dependence of the Nature of the Hydride Ligand on the Metal and the Bridging Diphosphorus Ligand.                                                                      
    J. S. Field, R. J. Haines, C. N. Sampson, J. Sundermeyer, K. G. Moodley, J. Organomet. Chem. 1987, 322, C7–C12. DOI: 10.1016/0022-328X(87)85033-7

    5. Contrasting Halogenating Action of Halogenoalkanes and Halogens towards Diphosphazane - Bridged Derivatives of Iron and Ruthenium Nonacarbonyl.  Crystal Structure of [Ru2Cl2(CO)4{m-(MeO)2P(NEt)-P(OMe)2}2].                                                                      
    J. S. Field, R. J. Haines, C. N. Sampson, J. Sundermeyer, J. Organomet. Chem. 1986, 310, C42–C46. DOI: 10.1016/S0022-328X(00)99565-2

    4. Halogenation and Stepwise Decarbonylation of  Diphosphazane-Bridged Derivates of Iron and Ruthenium Nonacarbonyl.  Crystal Structures of [Fe2I(CO)5{m-(MeO)2P(NEt)P(OMe)2}2]PF6 and [Ru2(m-I)I(CO)3{m-(iPrO)2P(NEt)P(OiPr)2}].                                                                      
    J. S. Field, R. J. Haines, E. Minshall, C.N. Sampson, J. Sundermeyer, C. C. Allen, J. C. A. Boeyens, J. Organomet. Chem. 1986, 309, C21–C25. DOI: 10.1016/S0022-328X(00)99595-0

    3. Reaktionen von 1,2,4-Thiadiazol-3,5-dicarbonitril mit Schwefelchloriden: Röntgenstrukturanalyse von S3(CN)4Cl2 (AsF5) und S3(CN)8Cl2.                                                                      
    H. W. Roesky, J. Sundermeyer, J. Schimkowiak, T. Gries, M. Noltemeyer, G. M. Sheldrick, Z. Naturforsch. 1986, 41B, 162–166. pdf

    2. Darstellung und Struktur des N-Thiobis-N'-(phenylsulfonyl)-schwefeldiimids.                                                                      
    H. W. Roesky, J. Sundermeyer, M. Noltemeyer, G. M. Sheldrick, K. Mayer-Bäse, P. G. Jones, Z. Naturforsch. 1986, 41B, 53–58. pdf

    1. Facile Synthesis and Crystal Structure of [(PhSO2N)2WCl2(CH3CN)2]  - the Oxidative Imination of W(CO)6 by N,N-Dichlorophenylsulphonamide.                                                                      
    H. W. Roesky, J. Sundermeyer, J. Schimkowiak, P. G. Jones, M. Noltemeyer, T. Schroeder, G. M. Sheldrick, Z. Naturforsch. 1985, 40B, 736–739. pdf

last edit: 06/2022